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JEE Main 2021 February 25, Shift 1 Question Paper with Solutions
All 90 questions from the JEE Main 2021 (February 25, Shift 1) shift — Physics (30), Chemistry (30) and Mathematics (30) — with the correct answer and a step-by-step solution for every question.
Physics30 questions
Q1Single correctVector Algebra
In an octagon ABCDEFGH of equal side, what is the sum of , if,

(A)
(B)
(C)
(D)
SolutionAnswer: Option 1
Approach:
For a regular octagon, the sum of the position vectors of all vertices taken from one vertex equals the number of vertices times the vector from that vertex to the centre.
Step 1:
Step 2:
Final answer:
Q2Single correctUnits and Measurements
Match List - I with List - II :
| List - I | List - II |
|---|---|
| (a). (Planck's constant) | (i). |
| (b). (kinetic energy) | (ii). |
| (c). (electric potential) | (iii). |
| (d). (linear momentum) | (iv). |
(A)
(B)
(C)
(D)
SolutionAnswer: Option 1(a) (ii), (b) (iii), (c) (iv), (d) (i)
Approach:
Determine the dimensional formula of each quantity in List-I and match against List-II.
Step 1:
Step 2:
Step 3:
Step 4:
, the only remaining choice is (iii)
Final answer: (a) (ii), (b) (iii), (c) (iv), (d) (i)
Q3Single correctKinematics
An engine of a train, moving with uniform acceleration, passes the signal-post with velocity and the last compartment with velocity . The velocity with which middle point of the train passes the signal post is :
(A)
(B)
(C)
(D)
SolutionAnswer: Option 2
Approach:
Use the kinematic relation for uniform acceleration over the half length of the train, which equals half the distance over which velocity changes from u to v.
Step 1:
over full length L
Step 2:
Step 3:
Final answer:
Q4Single correctGravitation
A solid sphere of radius R gravitationally attracts a particle placed at from its centre with a force . Now a spherical cavity of radius is made in the sphere (as shown in figure) and the force becomes . The value of is:

(A)
(B)
(C)
(D)
SolutionAnswer: Option 2
Approach:
Treat the cavity by superposition: the force of the cavity-sphere equals the force of the full sphere minus the force of a small sphere of the removed mass acting from the cavity centre.
Step 1:
Step 2:
removed mass , cavity centre at from O, distance to particle
Step 3:
Step 4:
Final answer:
Q5Single correctGravitation
Two satellites A and B of masses 200 kg and 400 kg are revolving round the earth at height of 600 km and 1600 km respectively. If and are the time periods of A and B respectively then the value of :
[ Given : radius of earth = 6400 km, mass of earth = kg ]
[ Given : radius of earth = 6400 km, mass of earth = kg ]

(A)
(B)
(C)
(D)
SolutionAnswer: Option 3 s
Approach:
Use Kepler's third law for circular orbits to find each period from its orbital radius, then take the difference.
Step 1:
Step 2:
Step 3:
Step 4:
Step 5:
Final answer: s
Q6Single correctGravitation
Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R.
Assertion A : The escape velocities of planet A and B are same. But A and B are of unequal mass.
Reason R: The product of their mass and radius must be same. In the light of the above statements, choose the most appropriate answer from the options given below :
Assertion A : The escape velocities of planet A and B are same. But A and B are of unequal mass.
Reason R: The product of their mass and radius must be same. In the light of the above statements, choose the most appropriate answer from the options given below :
(A)
(B)
(C)
(D)
SolutionAnswer: Option 4 is correct but is not correct
Approach:
Compare the escape-velocity condition with the relation stated in the Reason.
Step 1:
Equal escape velocities give
Step 2:
The Reason states , which is the product, not the ratio
Step 3:
Unequal masses can still satisfy equal, so the Assertion is consistent
Final answer: is correct but is not correct
Q7Single correctProperties of Solids and Liquids
Given below are two statements: one is labelled as Assertion and the other is labelled as Reason .
Assertion : When a rod lying freely is heated, no thermal stress is developed in it.
Reason : On heating, the length of the rod increases.
In the light of the above statements, choose the correct answer from the options given below:
Assertion : When a rod lying freely is heated, no thermal stress is developed in it.
Reason : On heating, the length of the rod increases.
In the light of the above statements, choose the correct answer from the options given below:
(A)
(B)
(C)
(D)
SolutionAnswer: Option 3Both and are true but is NOT the correct explanation of
Approach:
Judge the truth of each statement and whether the Reason explains the Assertion.
Step 1:
A freely lying rod expands without constraint, so no thermal stress develops: is true
Step 2:
On heating the rod's length increases: is true
Step 3:
The absence of stress is due to the rod being unconstrained, not merely due to length increase, so does not explain
Final answer: Both and are true but is NOT the correct explanation of
Q8Single correctKinetic Theory of Gases
A diatomic gas, having and , is heated at constant pressure. The ratio dU : dQ : dW
(A)
(B)
(C)
(D)
SolutionAnswer: Option 3
Approach:
At constant pressure, express each energy term using the molar heat capacities and the first law of thermodynamics.
Step 1:
Step 2:
Step 3:
Step 4:
Final answer:
Q9Single correctOscillations and Waves
If the time period of a two meter long simple pendulum is 2 s, the acceleration due to gravity at the place where pendulum is executing S.H.M. is:
(A)
(B)
(C)
(D)
SolutionAnswer: Option 1 m
Approach:
Use the simple pendulum period formula and solve for g.
Step 1:
Step 2:
Final answer: m
Q10Single correctOscillations and Waves
A student is performing the experiment of the resonance column. The diameter of the column tube is 6 cm. The frequency of the tuning fork is 504 Hz. Speed of the sound at the given temperature is 336 m . The zero of the meter scale coincides with the top end of the resonance column tube. The reading of the water level in the column when the first resonance occurs is:
(A)
(B)
(C)
(D)
SolutionAnswer: Option 1 cm
Approach:
For a closed pipe the first resonance length equals a quarter wavelength minus the end correction (0.6 times the tube radius).
Step 1:
Step 2:
Step 3:
Step 4:
Final answer: cm
Q11Single correctMagnetic Effects of Current and Magnetism
A proton, a deuteron and an particle are moving with same momentum in a uniform magnetic field. The ratio of magnetic forces acting on them ______ is and their speed is ______ in the ratio.
(A)
(B)
(C)
(D)
SolutionAnswer: Option 1 and
Approach:
Express the magnetic force and speed for equal momentum in terms of charge and mass of each particle.
Step 1:
Charges and masses
Step 2:
Step 3:
Final answer: and
Q12Single correctMagnetic Effects of Current and Magnetism
Magnetic fields at two points on the axis of a circular coil at a distance of m and m from the centre are in the ratio . The radius of coil is ______ .
(A)
(B)
(C)
(D)
SolutionAnswer: Option 3 m
Approach:
Use the on-axis field of a circular coil and form the ratio at the two distances.
Step 1:
Step 2:
Step 3:
Step 4:
Final answer: m
Q13Single correctElectromagnetic Induction and Alternating Currents
The current (i) at time and respectively for the given circuit is :

(A)
(B)
(C)
(D)
SolutionAnswer: Option 2
Approach:
At t=0 the inductor blocks current (open branch); at t=∞ the inductor behaves as a short circuit. Reduce the resistor network for each case to find the battery current.
Step 1:
At inductor open: path in parallel with
Step 2:
Step 3:
At inductor shorts the two side nodes:
Step 4:
Final answer:
Q14Single correctElectromagnetic Induction and Alternating Currents
The angular frequency of alternating current in a L-C-R circuit is 100 rad . The components connected are shown in the figure. Find the value of inductance of the coil and capacity of condenser.

(A)
(B)
(C)
(D)
SolutionAnswer: Option 4 H and F
Approach:
The same series current flows through every element. Find that current from the resistor whose voltage and resistance are both given, then obtain the reactances from the stated voltages across L and C.
Step 1:
Step 2:
Step 3:
Final answer: H and F
Q15Single correctOptics
Two coherent light sources having intensity in the ratio produce an interference pattern. The ratio will be
(A)
(B)
(C)
(D)
SolutionAnswer: Option 3
Approach:
Use the fringe-visibility expression in terms of the two intensities, substituting their given ratio.
Step 1:
, take
Step 2:
Final answer:
Q16Single correctDual Nature of Matter and Radiation
An particle and a proton are accelerated from rest by a potential difference of 200 V. After this, their de Broglie wavelengths are and respectively. The ratio is :
(A)
(B)
(C)
(D)
SolutionAnswer: Option 3
Approach:
Apply the de Broglie relation for a charged particle accelerated through a potential difference and take the ratio for the two particles.
Step 1:
Step 2:
Step 3:
Final answer:
Q17Single correctAtoms and Nuclei
Two radioactive substances X and Y originally have and nuclei respectively. Half life of X is half of the half life of Y. After three half lives of Y, number of nuclei of both are equal. The ratio will be equal to :
(A)
(B)
(C)
(D)
SolutionAnswer: Option 2
Approach:
Express the remaining nuclei of each substance after the elapsed time in terms of its own half life and set them equal.
Step 1:
Step 2:
Step 3:
Step 4:
Final answer:
Q18Single correctElectronic Devices
A 5 V battery is connected across the points X and Y. Assume and to be normal silicon diodes. Find the current supplied by the battery if the terminal of the battery is connected to point X.

(A)
(B)
(C)
(D)
SolutionAnswer: Option 4 A
Approach:
Determine which diode is forward biased for the given battery polarity and compute the current through the conducting branch using the silicon diode drop of 0.7 V.
Step 1:
is forward biased, is reverse biased
Step 2:
Step 3:
Final answer: A
Q19Single correctElectromagnetic Waves
Given below are two statements:
Statement I : A speech signal of 2 kHz is used to modulate a carrier signal of 1 MHz. The bandwidth requirement for the signal is 4 kHz.
Statement II : The side band frequencies are 1002 kHz and 998 kHz. In the light of the above statements, choose the correct answer from the options given below:
Statement I : A speech signal of 2 kHz is used to modulate a carrier signal of 1 MHz. The bandwidth requirement for the signal is 4 kHz.
Statement II : The side band frequencies are 1002 kHz and 998 kHz. In the light of the above statements, choose the correct answer from the options given below:
(A)
(B)
(C)
(D)
SolutionAnswer: Option 2Both Statement I and Statement II are true
Approach:
Compute the amplitude-modulation bandwidth and the upper and lower side band frequencies and compare with both statements.
Step 1:
Step 2:
Step 3:
Final answer: Both Statement I and Statement II are true
Q20Single correctExperimental Skills
The pitch of the screw gauge is 1 mm and there are 100 divisions on the circular scale. When nothing is put in between the jaws, the zero of the circular scale lies 8 divisions below the reference line. When a wire is placed between the jaws, the first linear scale division is clearly visible while division on circular scale coincides with the reference line. The radius of the wire is
(A)
(B)
(C)
(D)
SolutionAnswer: Option 2 mm
Approach:
Find the least count, the positive zero error, the observed diameter, correct it, then halve to get the radius.
Step 1:
Step 2:
Step 3:
Step 4:
Step 5:
Final answer: mm
Q21NumericalLaws of Motion
A small bob tied at one end of a thin string of length 1 m is describing a vertical circle so that the maximum and minimum tension in the string are in the ratio 5 : 1. The velocity of the bob at the highest position is _____ m . (Take m )
SolutionAnswer: 5
Approach:
Write the tensions at the lowest and highest points, relate the speeds by energy conservation, and apply the given tension ratio.
Step 1:
Step 2:
Step 3:
Step 4:
Final answer:
Q22NumericalWork, Energy and Power
The potential energy (U) of a diatomic molecule is a function dependent on r (interatomic distance) as where and are positive constants. The equilibrium distance between two atoms will be , where _____ .
SolutionAnswer: 1
Approach:
Set the derivative of the potential energy with respect to interatomic distance to zero to obtain the equilibrium separation.
Step 1:
Step 2:
Step 3:
Final answer:
Q23NumericalThermodynamics
In a certain thermodynamical process, the pressure of a gas depends on its volume as . The work done when the temperature changes from 100 C to 300 C will be xnR where n denotes number of moles of a gas find x :
SolutionAnswer: 50
Approach:
Express pressure and the ideal gas relation, integrate pressure over volume to find the work, and reduce it to the form xnR using the temperature change.
Step 1:
Step 2:
Step 3:
Step 4:
Final answer:
Q24NumericalKinetic Theory of Gases
A monoatomic gas of mass is kept in an insulated container. The container is moving with velocity 30 m . If the container is suddenly stopped then a change in temperature of the gas (gas constant) is . Value of x is,
SolutionAnswer: 3600
Approach:
Equate the bulk kinetic energy of the gas, lost when the container stops, to the increase in internal energy of the monoatomic gas.
Step 1:
Step 2:
Step 3:
Final answer:
Q25NumericalElectrostatics
The electric field in a region is given by N . The ratio of flux of reported field through the rectangular surface of area (parallel to plane) to that of the surface of area (parallel to plane) is , where ? [Here , and are unit vectors along x, y and z -axes respectively]
SolutionAnswer: 1
Approach:
Compute the flux through each surface using the component of the field along the respective surface normal and take the ratio.
Step 1:
Step 2:
Step 3:
Final answer:
Q26NumericalElectrostatics
512 identical drops of mercury are charged to a potential of 2 V each. The drops are joined to form a single drop. The potential of this drop is in Volt.
SolutionAnswer: 128
Approach:
Conserve total charge and total volume on combining the drops, then express the potential of the big drop in terms of that of a small drop.
Step 1:
Step 2:
Step 3:
Final answer:
Q27NumericalCurrent Electricity
In the given circuit of potentiometer, the potential difference E across AB(10 m length) is larger than and as well. For key (closed), the jockey is adjusted to touch the wire at point so that there is no deflection in the galvanometer. Now the first battery () is replaced by second battery () for working by making open and closed. The galvanometer gives then null deflection at . The value of is , where _____ .

SolutionAnswer: 1
Approach:
Use the potentiometer balance condition that the unknown EMF is proportional to the balancing length from A, reading the balancing lengths of J1 and J2 from the snake-wire layout.
Step 1:
Step 2:
Step 3:
Step 4:
Final answer:
Q28NumericalElectromagnetic Induction and Alternating Currents
A coil of inductance 2 H having negligible resistance is connected to a source of supply whose voltage is given by volt. (where is in second). If the voltage is applied when , then the energy stored in the coil after 4 s in J,
SolutionAnswer: 144
Approach:
Use the inductor voltage relation to find the current as a function of time, evaluate it at 4 s, and compute the magnetic energy stored.
Step 1:
Step 2:
Step 3:
Step 4:
Final answer:
Q29NumericalElectromagnetic Induction and Alternating Currents
A transmitting station releases waves of wavelength 960 m. A capacitor of F is used in the resonant circuit. The self-inductance of coil necessary for resonance is H. find x
SolutionAnswer: 10
Approach:
Relate the wavelength to the resonant period of the LC circuit, solve for the product LC, and extract the inductance.
Step 1:
Step 2:
Step 3:
Step 4:
Final answer:
Q30NumericalOptics
The same size images are formed by a convex lens when the object is placed at 20 cm or at 10 cm from the lens. The focal length of convex lens is _____ .
SolutionAnswer: 15
Approach:
Equate the magnitudes of the magnifications for the real image (object beyond focus) and the virtual image (object inside focus), with opposite signs, and solve for the focal length.
Step 1:
Step 2:
Step 3:
Final answer:
Chemistry30 questions
Q31Single correctPurification and Characterisation of Organic Compounds
Complete combustion of 1.80 g of an oxygen containing compound gave 2.64 g of and 1.08 g of . The percentage of oxygen in the organic compound is :
(A)
(B)
(C)
(D)
SolutionAnswer: Option 1
Approach:
Determine the mass of carbon and hydrogen from the combustion products, obtain oxygen mass by difference, and express it as a percentage of the sample mass.
Step 1:
Step 2:
Step 3:
Step 4:
Final answer:
Q32Single correctAtomic Structure
The plots of radial distribution functions for various orbitals of hydrogen atom against ' ' are given below.
The correct plot for the 3s orbital is :
The correct plot for the 3s orbital is :
(A)
(B)
(C)
(D)
SolutionAnswer: Option 3
Approach:
Count the number of radial maxima and radial nodes characteristic of the 3s orbital and match it to the plot.
Step 1:
Step 2:
Step 3:
Final answer:
Q33Single correctChemical Bonding and Molecular Structure
According to molecular orbital theory, the species among the following that does not exist is :
(A)
(B)
(C)
(D)
SolutionAnswer: Option 4
Approach:
Compute the bond order of each species from its molecular orbital electron count; a species with zero bond order does not exist.
Step 1:
Step 2:
Step 3:
Step 4:
Final answer:
Q34Single correctEquilibrium
The solubility of AgCN in a buffer solution of pH is x. The value of x is : [Assume : No cyano complex is formed; and ]
(A)
(B)
(C)
(D)
SolutionAnswer: Option 1
Approach:
Account for protonation of the dissolved cyanide ion at pH 3, relate the free cyanide fraction to the solubility, and solve the modified solubility product expression.
Step 1:
Step 2:
Step 3:
Step 4:
Final answer:
Q35Single correctp-Block Elements
Which of the following equation depicts the oxidizing nature of ?
(A)
(B)
(C)
(D)
SolutionAnswer: Option 1
Approach:
Track the oxidation states; H2O2 acts as an oxidant when it is itself reduced (oxygen from -1 to -2) while oxidizing the other species.
Step 1:
Step 2:
Step 3:
Final answer:
Q36Single correctp-Block Elements
The incorrect statement about is :
(A)
(B)
(C)
(D)
SolutionAnswer: Option 1All angles are of
Approach:
Recall the structure of diborane and evaluate each statement against the known bridge geometry and bonding of B2H6.
Step 1:
Step 2:
Step 3:
Step 4:
Final answer: All angles are of
Q37Single correctOrganic Compounds Containing Oxygen
Compound(s) which will liberate carbon dioxide with sodium bicarbonate solution is/are :
A, B and C are the structures shown.
A, B and C are the structures shown.

(A)
(B)
(C)
(D)
SolutionAnswer: Option 2B and C only
Approach:
Sodium bicarbonate liberates carbon dioxide only with acids stronger than carbonic acid; identify which structures are sufficiently acidic.
Step 1:
Step 2:
Step 3:
Final answer: B and C only
Q38Single correctHydrocarbons
Identify A in the given chemical reaction.
The branched chain hydrocarbon (drawn structure) is heated over at 773 K, 10-20 atm to give 'A' as the major product.
The branched chain hydrocarbon (drawn structure) is heated over at 773 K, 10-20 atm to give 'A' as the major product.

(A)
(B)
(C)
(D)
SolutionAnswer: Option 4
Approach:
Recognize the reaction as catalytic aromatization (reforming) of a seven-carbon alkane over Mo2O3, which cyclises and dehydrogenates the chain to an aromatic product.
Step 1:
Step 2:
Step 3:
Final answer:
Q39Single correctOrganic Compounds Containing Nitrogen
Which of the following reaction/s will not give -aminoazobenzene?
Reactions of nitro/amino benzene derivatives A, B and C are shown with the reagents indicated.
Reactions of nitro/amino benzene derivatives A, B and C are shown with the reagents indicated.

(A)
(B)
(C)
(D)
SolutionAnswer: Option 1B only
Approach:
Trace each sequence to see whether a diazonium salt is generated that can couple with aniline to form p-aminoazobenzene; the route lacking nitrous acid diazotisation fails.
Step 1:
Step 2:
Step 3:
Final answer: B only
Q40Single correctOrganic Compounds Containing Halogens
Identify A and B in the chemical reaction.
The starting material (drawn structure) reacts with to give (major), which then reacts with in dry acetone to give major.
The starting material (drawn structure) reacts with to give (major), which then reacts with in dry acetone to give major.

(A)
(B)
(C)
(D)
SolutionAnswer: Option 2
Approach:
Apply Markovnikov addition of HCl across the ring double bond to obtain A, then Finkelstein exchange of chloride by iodide with NaI in dry acetone to obtain B, and match the regiochemistry to the option.
Step 1:
Step 2:
Step 3:
Final answer:
Q41Single correctp-Block Elements
Given below are two statements:
Statement I : An allotrope of oxygen is an important intermediate in the formation of reducing smog.
Statement II : Gases such as oxides of nitrogen and sulphur present in troposphere contribute to the formation of photochemical smog. In the light of the above statements, choose the correct answer from the options given below:
Statement I : An allotrope of oxygen is an important intermediate in the formation of reducing smog.
Statement II : Gases such as oxides of nitrogen and sulphur present in troposphere contribute to the formation of photochemical smog. In the light of the above statements, choose the correct answer from the options given below:
(A)
(B)
(C)
(D)
SolutionAnswer: Option 1Both Statement I and Statement II are false
Approach:
Evaluate each statement against the definitions of reducing (classical) smog and photochemical (oxidising) smog.
Step 1:
Step 2:
Final answer: Both Statement I and Statement II are false
Q42Single correctp-Block Elements
In Freundlich adsorption isotherm at moderate pressure, the extent of adsorption is directly proportional to . The value of x is :
(A)
(B)
(C)
(D)
SolutionAnswer: Option 2
Approach:
Recall the Freundlich isotherm and identify the pressure exponent in the moderate-pressure regime.
Step 1:
Step 2:
Final answer:
Q43Single correctd- and f-Block Elements
Ellingham diagram is a graphical representation of :
(A)
(B)
(C)
(D)
SolutionAnswer: Option 4 vs T
Approach:
Recall the definition of the Ellingham diagram used in metallurgy.
Step 1:
Final answer: vs T
Q44Single correctd- and f-Block Elements
Given below are two statements:
Statement I : can be used for oxidation of aldehydes and ketones.
Statement II : Aqueous solution of is a strong reducing agent. In the light of the above statements, choose the correct answer from the options given below:
Statement I : can be used for oxidation of aldehydes and ketones.
Statement II : Aqueous solution of is a strong reducing agent. In the light of the above statements, choose the correct answer from the options given below:
(A)
(B)
(C)
(D)
SolutionAnswer: Option 1Both Statement I and Statement II are true
Approach:
Assess the oxidising ability of cerium(IV) and the reducing ability of europium(II) from lanthanide chemistry.
Step 1:
Step 2:
Final answer: Both Statement I and Statement II are true
Q45Single correctd- and f-Block Elements
In which of the following pairs, the outermost electronic configuration will be the same?
(A)
(B)
(C)
(D)
SolutionAnswer: Option 1 and
Approach:
Write the d-electron configuration of each ion and find the pair sharing the identical outermost configuration.
Step 1:
Step 2:
Step 3:
Step 4:
Final answer: and
Q46Single correctCoordination Compounds
The hybridization and magnetic nature of and , respectively are :
(A)
(B)
(C)
(D)
SolutionAnswer: Option 2 and paramagnetic
Approach:
Determine oxidation state and d-electron count of the central metal, apply strong-field CN- pairing, then assign hybridization and magnetic nature.
Step 1:
Step 2:
Step 3:
Step 4:
Final answer: and paramagnetic
Q47Single correctOrganic Compounds Containing Oxygen
Which one of the following reactions will not form acetaldehyde?
(A)
(B)
(C)
(D)
SolutionAnswer: Option 1
Approach:
Identify the product of each oxidation/reduction route from ethanol or its equivalent, then locate the one that does not give acetaldehyde.
Step 1:
Step 2:
(Wacker)
Step 3:
Step 4:
Final answer:
Q48Single correctOrganic Compounds Containing Oxygen
The major product of the following chemical reaction is :
(A)
(B)
(C)
(D)
SolutionAnswer: Option 1
Approach:
Carry the nitrile through acid hydrolysis, acyl chloride formation, and Rosenmund reduction step by step.
Step 1:
Step 2:
Step 3:
Final answer:
Q49Single correctSome Basic Principles of Organic Chemistry
Which statement is correct?
(A)
(B)
(C)
(D)
SolutionAnswer: Option 1Synthesis of Buna-S needs nascent oxygen.
Approach:
Evaluate each statement against the known nature and synthesis of Buna-S, Buna-N and Neoprene.
Step 1:
Step 2:
Step 3:
Step 4:
Final answer: Synthesis of Buna-S needs nascent oxygen.
Q50Single correctBiomolecules
Which of the glycosidic linkage between galactose and glucose is present in lactose?
(A)
(B)
(C)
(D)
SolutionAnswer: Option 3 of galactose and of glucose
Approach:
Recall the structure of lactose and the carbon atoms involved in its glycosidic bond.
Step 1:
Step 2:
Final answer: of galactose and of glucose
Q51NumericalSome Basic Concepts in Chemistry
A car tyre is filled with nitrogen gas at 35 psi at . It will burst if pressure exceeds 40 psi. The temperature in at which the car tyre will burst is (Rounded-off to the nearest integer)
SolutionAnswer: 70
Approach:
Apply Gay-Lussac's law at constant volume to find the bursting temperature.
Step 1:
Step 2:
Step 3:
Final answer: 70
Q52NumericalChemical Thermodynamics
The reaction of cyanamide, with oxygen was run in a bomb calorimeter and was found to be . The magnitude of for the reaction
is kJ. (Rounded off to the nearest integer) [Assume ideal gases and ]
is kJ. (Rounded off to the nearest integer) [Assume ideal gases and ]
SolutionAnswer: 741
Approach:
Relate enthalpy and internal energy change through the change in gaseous moles and report the magnitude.
Step 1:
Step 2:
Step 3:
Step 4:
Final answer: 741
Q53NumericalChemical Thermodynamics
The ionization enthalpy of formation from is , while the electron gain enthalpy of Br is . Given the lattice enthalpy of NaBr is . The energy for the formation of NaBr ionic solid is ______
SolutionAnswer: 5576
Approach:
Sum the ionization enthalpy, electron gain enthalpy and lattice enthalpy, then express the magnitude in units of kJ/mol.
Step 1:
Step 2:
Step 3:
Final answer: 5576
Q54NumericalSome Basic Concepts in Chemistry
mixture of NaOH, and some inert impurities was first titrated with HCl using phenolphthalein as an indicator, of HCl was required at the end point. After this methyl orange was added and titrated. of same HCl was required for the next end point. The weight percentage of in the mixture is (Rounded-off to the nearest integer)
SolutionAnswer: 4
Approach:
Use the methyl orange volume (second stage of carbonate) to find moles of Na2CO3, then compute its mass percentage.
Step 1:
Step 2:
Step 3:
Step 4:
Final answer: 4
Q55NumericalRedox Reactions and Electrochemistry
In basic medium oxidises to form and itself changes into . The volume of required to react with of is ______ mL. (Rounded-off to the nearest integer)
SolutionAnswer: 173
Approach:
Balance the electron transfer for each species and equate equivalents to find the required volume.
Step 1:
Step 2:
Step 3:
Step 4:
Final answer: 173
Q56NumericalPurification and Characterisation of Organic Compounds
Using the provided information in the following paper chromatogram:
The calculated value of A is ______ .
The calculated value of A is ______ .

SolutionAnswer: 4
Approach:
Read the distances of spot A and of the solvent front from the chromatogram and apply the Rf definition.
Step 1:
Step 2:
Step 3:
Final answer: 4
Q57NumericalHydrocarbons
Consider the following chemical reaction.
The number of hybridized carbon atom(s) present in the product is
The number of hybridized carbon atom(s) present in the product is
SolutionAnswer: 7
Approach:
Identify the product of the trimerisation followed by Gattermann-Koch formylation, then count its sp2 carbons.
Step 1:
Step 2:
Step 3:
Final answer: 7
Q58NumericalSolutions
1 molal aqueous solution of an electrolyte is 60% ionised. The boiling point of the solution at 1 atm is ______ K. (Rounded-off to the nearest integer) [Given for ]
SolutionAnswer: 375
Approach:
Compute the van't Hoff factor from the degree of ionisation, find the boiling point elevation and add it to the normal boiling point of water.
Step 1:
Step 2:
Step 3:
Step 4:
Final answer: 375
Q59NumericalChemical Kinetics
For the reaction, , the plot of v/s is given below:
The temperature at which the rate constant of the reaction is is ______ K. (Rounded-off to the nearest integer) [Given : The rate constant of the reaction is at 500 K.]
The temperature at which the rate constant of the reaction is is ______ K. (Rounded-off to the nearest integer) [Given : The rate constant of the reaction is at 500 K.]

SolutionAnswer: 526
Approach:
Use the slope of the Arrhenius plot to relate the two rate constants at two temperatures and solve for the unknown temperature.
Step 1:
Step 2:
Step 3:
Step 4:
Final answer: 526
Q60Numericalp-Block Elements
Among the following, the number of halide(s) which is/ are inert to hydrolysis is
(A)
(B)
(C)
(D)
(A)
(B)
(C)
(D)
SolutionAnswer: 1
Approach:
Examine each halide for the availability of an empty orbital or coordination site that allows attack by water.
Step 1:
Step 2:
Step 3:
Step 4:
Final answer: 1
Mathematics30 questions
Q61Single correctComplex Numbers and Quadratic Equations
The integer k, for which the inequality is valid for every x in R is:
(A)
(B)
(C)
(D)
SolutionAnswer: Option 3
Approach:
A monic quadratic is positive for all real exactly when its discriminant is negative.
Step 1:
Step 2:
Step 3:
Step 4:
Final answer:
Q62Single correctCo-ordinate Geometry
Let the lines and , (here ) be normal to a circle C. If the line is tangent to this circle C, then its radius is :
(A)
(B)
(C)
(D)
SolutionAnswer: Option 3
Approach:
Two normals meet at the centre; the radius is the distance from the centre to the tangent line. Write each complex equation as a real Cartesian line using .
Step 1:
Step 2:
Step 3:
Step 4:
Step 5:
Final answer:
Q63Single correctPermutations and Combinations
The total number of positive integral solutions (x,\ y,\ z) such that is :
(A)
(B)
(C)
(D)
SolutionAnswer: Option 2
Approach:
Factorise 24 into primes and distribute each prime's exponent among three variables using stars and bars.
Step 1:
Step 2:
Step 3:
Final answer:
Q64Single correctSequence and Series
If , , and then :
(A)
(B)
(C)
(D)
SolutionAnswer: Option 3
Approach:
Sum each infinite geometric series, then verify the algebraic relation among x, y and z.
Step 1:
Step 2:
Step 3:
Step 4:
Step 5:
Final answer:
Q65Single correctTrigonometry
All possible values of for which lie in :
(A)
(B)
(C)
(D)
SolutionAnswer: Option 3
Approach:
Rewrite the expression as a single fraction and determine the sign over each quadrant of .
Step 1:
Step 2:
Step 3:
Step 4:
Final answer:
Q66Single correctCo-ordinate Geometry
The image of the point in the line , lies on :
(A)
(B)
(C)
(D)
SolutionAnswer: Option 1
Approach:
Reflect the point across the line, then test which circle the image satisfies.
Step 1:
Step 2:
Step 3:
Final answer:
Q67Single correctCo-ordinate Geometry
A tangent is drawn to the parabola which is perpendicular to the line . Which of the following points does NOT lie on it?
(A)
(B)
(C)
(D)
SolutionAnswer: Option 3
Approach:
Find the tangent slope from perpendicularity, write the tangent to the parabola with that slope, then test each point.
Step 1:
has slope , so tangent slope
Step 2:
Step 3:
Step 4:
Final answer:
Q68Single correctCo-ordinate Geometry
If the curves, and intersect each other at an angle of , then which of the following relations is TRUE?
(A)
(B)
(C)
(D)
SolutionAnswer: Option 2
Approach:
Conics intersecting orthogonally at every common point have equal differences of their denominators (confocal-type condition).
Step 1:
At a common point the tangents are perpendicular, giving the relation among coefficients
Step 2:
Subtracting the curve equations at the intersection point yields
Final answer:
Q69Single correctLimit, Continuity and Differentiability
is equal to
(A)
(B)
(C)
(D)
SolutionAnswer: Option 4
Approach:
Use the form: the limit equals of n times the small quantity, where the harmonic sum grows like .
Step 1:
since
Step 2:
Final answer:
Q70Single correctSets, Relations and Functions
The statement is equivalent to :
(A)
(B)
(C)
(D)
SolutionAnswer: Option 2
Approach:
Simplify the given statement to a tautology, then identify which option is also a tautology.
Step 1:
Step 2:
Final answer:
Q71Single correctTrigonometry
A man is observing, from the top of a tower, a boat speeding towards the tower from a certain point A, with uniform speed. At that point, angle of depression of the boat with the man's eye is (Ignore man's height). After sailing for 20 seconds, towards the base of the tower (which is at the level of water), the boat has reached a point B, where the angle of depression is . Then the time taken (in seconds) by the boat from B to reach the base of the tower is :
(A)
(B)
(C)
(D)
SolutionAnswer: Option 4
Approach:
Express horizontal distances at the two depression angles in terms of the tower height, use the uniform speed from the 20-second leg, then find the time for the remaining distance.
Step 1:
Step 2:
Step 3:
Final answer:
Q72Single correctSets, Relations and Functions
Let such that and g be any arbitrary function. Which of the following statements is NOT true?
(A)
(B)
(C)
(D)
SolutionAnswer: Option 2If g is onto, then is one-one
Approach:
The recurrence forces to be linear; test each statement using injectivity of and properties of composition.
Step 1:
Step 2:
f onto
Step 3:
one-one one-one (since f injective)
Step 4:
g onto does not force g one-one, so need not be one-one
Final answer: If g is onto, then is one-one
Q73Single correctLimit, Continuity and Differentiability
If Rolle's theorem holds for the function with , then ordered pair (a,\ b) is equal to :
(A)
(B)
(C)
(D)
SolutionAnswer: Option 3
Approach:
Rolle's theorem requires , and the stationary point at gives a second equation; solve for and .
Step 1:
Step 2:
Step 3:
Solving:
Final answer:
Q74Single correctIntegral Calculus
The value of the integral is (where c is a constant of integration)
(A)
(B)
(C)
(D)
SolutionAnswer: Option 3
Approach:
Use and to reduce the integrand, then substitute .
Step 1:
Integrand
Step 2:
Step 3:
Antiderivative rewritten via
Step 4:
Result
Final answer:
Q75Single correctIntegral Calculus
The value of , where [t] denotes the greatest integer , is :
(A)
(B)
(C)
(D)
SolutionAnswer: Option 4
Approach:
Split the interval where is constant: on and on .
Step 1:
Step 2:
Step 3:
Step 4:
Final answer:
Q76Single correctDifferential Equations
If a curve passes through the origin and the slope of the tangent to it at any point (x, y) is , then this curve also passes through the point:
(A)
(B)
(C)
(D)
SolutionAnswer: Option 4
Approach:
Treat the slope relation as a linear first-order ODE in y, solve using an integrating factor, fix the constant with the origin, and test the listed points.
Step 1:
Step 2:
Step 3:
Step 4:
Step 5:
Step 6:
Final answer:
Q77Single correctThree Dimensional Geometry
Let be the angle between the lines whose direction cosines satisfy the equations and . Then the value of is :
(A)
(B)
(C)
(D)
SolutionAnswer: Option 1
Approach:
Eliminate n using the linear relation, obtain the two direction sets, find the angle from their dot product, then evaluate the trigonometric expression.
Step 1:
Step 2:
Step 3:
Step 4:
Final answer:
Q78Single correctThree Dimensional Geometry
The equation of the line through the point and perpendicular to the line is :
(A)
(B)
(C)
(D)
SolutionAnswer: Option 3
Approach:
Each option line passes through (0,1,2); select the one whose direction vector is perpendicular to the given line's direction (2,3,-2).
Step 1:
Given direction
Step 2:
Step 3:
; ;
Final answer:
Q79Single correctStatistics and Probability
The coefficients a, b and c of the quadratic equation, are obtained by throwing a dice three times. The probability that this equation has equal roots is:
(A)
(B)
(C)
(D)
SolutionAnswer: Option 4
Approach:
Equal roots require the discriminant to vanish; count ordered triples (a,b,c) from 1-6 with =4ac and divide by 216.
Step 1:
Total outcomes
Step 2:
even
Step 3:
; ;
Step 4:
Final answer:
Q80Single correctStatistics and Probability
When a missile is fired from a ship, the probability that it is intercepted is and the probability that the missile hits the target, given that it is not intercepted, is . If three missiles are fired independently from the ship, then the probability that all three hit the target, is:
(A)
(B)
(C)
(D)
SolutionAnswer: Option 3
Approach:
Find the probability a single missile hits, then cube it for three independent missiles.
Step 1:
Step 2:
Final answer:
Q81NumericalPermutations and Combinations
The total number of numbers, lying between 100 and 1000 that can be formed with the digits , if the repetition of digits is not allowed and numbers are divisible by either 3 or 5, is _____ .
SolutionAnswer: 32
Approach:
Count three-digit numbers divisible by 3 and those divisible by 5 separately, then apply inclusion-exclusion for those divisible by both (i.e. by 15).
Step 1:
Divisible by 5 (last digit ):
Step 2:
Digit triples with sum divisible by 3: , each
Step 3:
Divisible by 15: triples containing with sum divisible by 3 are , last digit fixed 5:
Step 4:
Final answer: 32
Q82NumericalSequence and Series
Let be squares such that for each , the length of the side of equals the length of diagonal of . If the length of is 12 cm, then the smallest value of n for which area of is less than one, is _____ .
SolutionAnswer: 9
Approach:
Express the side of as a geometric sequence, write its area, and find the least n making the area below 1.
Step 1:
Step 2:
Step 3:
Final answer: 9
Q83NumericalCo-ordinate Geometry
The locus of the point of intersection of the lines and is a conic, whose eccentricity is _____ .
SolutionAnswer: 2
Approach:
Eliminate the parameter k from the two lines to obtain the locus, identify the conic, and compute its eccentricity.
Step 1:
and
Step 2:
Step 3:
Final answer: 2
Q84NumericalMatrices and Determinants
If and , then is equal to _____ .
SolutionAnswer: 13
Approach:
Compute (I+A) for the skew-symmetric A; the result is the rotation matrix [[cos,-sin],[sin,cos]], giving +.
Step 1:
Let ;
Step 2:
Step 3:
Final answer: 13
Q85NumericalMatrices and Determinants
Let , where x, y and z are real numbers such that and . If , then the value of is _____ .
SolutionAnswer: 7
Approach:
Use = to obtain relations among the symmetric functions of x,y,z, then apply the factorisation identity for the sum of cubes.
Step 1:
and
Step 2:
Step 3:
Final answer: 7
Q86NumericalMatrices and Determinants
If the system of equations
has infinitely many solutions, then k is equal to _____ .
has infinitely many solutions, then k is equal to _____ .
SolutionAnswer: 21
Approach:
The coefficient determinant vanishes for all k, so impose the consistency condition that the equations agree for infinitely many solutions to find k.
Step 1:
Third equation:
Step 2:
Adding to second:
Step 3:
First minus scaled third:
Step 4:
Final answer: 21
Q87NumericalLimit, Continuity and Differentiability
The number of points, at which the function is not differentiable, is _____ .
SolutionAnswer: 2
Approach:
Identify the corner candidates from each modulus argument and test each by comparing the derivative jumps, since cancelling jumps restore differentiability.
Step 1:
Candidates: (from and ), ,
Step 2:
At : jump from is ; jump from is ; total
Step 3:
At : jump ; at : jump
Step 4:
Non-differentiable at points
Final answer: 2
Q88NumericalLimit, Continuity and Differentiability
Let f(x) be a polynomial of degree 6 in x, in which the coefficient of is unity and it has extrema at and . If , then is equal to _____ .
SolutionAnswer: 144
Approach:
Use the limit to fix the lower-degree terms, then impose the extrema conditions to determine the remaining coefficients and evaluate 5 f(2).
Step 1:
(no constant terms; coefficient )
Step 2:
;
Step 3:
Step 4:
Step 5:
Final answer: 144
Q89NumericalIntegral Calculus
The graphs of sine and cosine functions, intersect each other at a number of points and between two consecutive points of intersection, the two graphs enclose the same area A. Then is equal to _____ .
SolutionAnswer: 64
Approach:
Integrate the absolute difference of sine and cosine between two consecutive intersection points to get A, then raise to the fourth power.
Step 1:
Consecutive intersections at and
Step 2:
Step 3:
Final answer: 64
Q90NumericalVector Algebra
Let , and be three given vectors. If is a vector such that and , then is equal to _____ .
SolutionAnswer: 12
Approach:
From the cross-product condition r differs from c by a multiple of a; apply the dot condition to fix the multiple, then compute r dot a.
Step 1:
Step 2:
Step 3:
Final answer: 12
